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Logs and petrophysicsLogging basics Intermediate 13 min read

Formation water and formation temperature

Formation water is the water that fills the pores of rocks underground (the pores are the small spaces between grains). Its salinity (salt content) ranges from almost fresh to strong brines, but the water is more often salty. For logging, the main property of formation water is its electrical resistivity RwR_w (how strongly it resists electric current). The resistivity depends on the salinity and the temperature. Formation temperature is the natural temperature of the rocks at the depth of the formation. We estimate it from the geothermal gradient (how fast temperature rises with depth) and from measurements in the well. We correct these measurements for the cooling of the bottom of the hole by the circulating mud.

Why it matters

The resistivities of water, filtrate (the liquid part of the drilling mud that enters the rock) and mud fall sharply when they are heated. Water whose resistivity was measured in the laboratory at 20 °C conducts current almost three times better in the formation at 100 °C. If we do not bring RwR_w to formation temperature, the water saturation from Archie's equation (the equation that turns resistivity into saturation) comes out too high by tens of per cent. A productive bed can then be mistaken for a water-bearing one. We also need temperature to calculate the spontaneous potential (SP), a natural voltage recorded in the well, to find the properties of oil, gas and water, and to select the drilling fluid, the cement and the downhole equipment.

Quick refresher

  • The ions (charged particles) of the salts in the formation water carry the current in a rock. The higher the salinity and the temperature, the lower the resistivity of the water, RwR_w, and of the rock.
  • We express salinity in g/L (the mass of salt in a litre of solution) or in ppm (milligrams of salt per kilogram of solution). The two differ by the density of the solution. Log interpretation uses the equivalent NaCl concentration (the concentration of an NaCl solution that conducts as well as the water).
  • When a solution is heated from 20 to 100 °C, its resistivity falls almost threefold. We bring all the resistivities (RwR_w, RmfR_{mf}, RmR_m) to formation temperature.
  • Temperature usually increases with depth by 2–4 °C per 100 m. Between the surface and the bottom of the hole we usually interpolate it linearly (along a straight line).
  • Circulating mud cools the bottom of the hole, so a temperature measured soon after circulation stops is below the formation temperature. If we take several readings over time, we can extrapolate (extend the trend) to the formation temperature.
Key relationships
R2=R1 T1+21.5T2+21.5R_2 = R_1\,\dfrac{T_1 + 21.5}{T_2 + 21.5}

conversion of the resistivity of an NaCl solution from temperature T1T_1 to T2T_2 (°C), the Arps formula

T(z)=T0+GT zT(z) = T_0 + G_T\,z

linear increase of temperature with depth; GTG_T is the geothermal gradient

Tbh(Δt)=Tres−mlg⁡tc+ΔtΔtT_{\text{bh}}(\Delta t) = T_{\text{res}} - m\lg\dfrac{t_c + \Delta t}{\Delta t}

recovery of the bottom-hole temperature after circulation stops (the Horner method)

Common pitfalls
  • Taking the resistivity of a sample at laboratory temperature as the formation RwR_w.
  • Treating the bottom-hole temperature measured on the first tool run as the formation temperature.
  • Confusing g/L and ppm: for brines the difference reaches 17%.
  • Estimating RwR_w from the total salinity of a water of complex composition as if it were a pure NaCl solution.

After this lesson you can

  • tell apart the water in the pores, the water bound to clays, and the water of crystallisation (water built into mineral crystals), and explain which of them determines RwR_w
  • express salinity in g/L, in ppm (parts per million) and as an equivalent NaCl concentration, and convert from one unit to another
  • estimate the resistivity of water from its salinity, and convert resistivity from one temperature to another
  • find the formation temperature from the geothermal gradient, and from several bottom-hole readings corrected for the effect of circulation
  • estimate how errors in temperature and salinity lead to errors in RwR_w and in water saturation

Water in the rock as the interpreter sees it

Formation evaluation comes down to three quantities. Porosity tells how much fluid the rock holds. Saturation tells what share of the pores water, oil and gas occupy. Permeability tells how easily the fluids move to the well. Logging measures none of them directly. We calculate them from the physical properties of the rock, and for that we need to know three “external” quantities: what the mineral matrix (the solid skeleton of the rock) is made of, what water is in the pores, and at what temperature the water is.

In interpretation we describe the mineral matrix by its chemical composition, not by grain size, because the composition determines the tool readings. That is why quartz siltstone and chert behave on logs like sandstone, chalk behaves like limestone, and gypsum differs sharply from anhydrite.

Rock classes in log interpretation
Class
Sandstone
Main mineral
quartz SiO₂
What belongs to it
also quartz siltstone, chert, conglomerate
Class
Limestone
Main mineral
calcite CaCO₃
What belongs to it
also chalk
Class
Dolomite
Main mineral
dolomite CaMg(CO₃)₂
What belongs to it
the readings differ noticeably from limestone
Class
Salt
Main mineral
halite NaCl
What belongs to it
rock salt, salt-bearing sequences
Class
Anhydrite, gypsum
Main mineral
CaSO₄; CaSO₄·2H₂O
What belongs to it
the water in gypsum crystals changes its readings sharply
Class
Shale
Main mineral
clay minerals
What belongs to it
clays and claystones, without telling the minerals apart

This is a simplified division, used to choose the parameters of the mineral matrix. The geological name of the rock may differ.

We must also tell the kinds of water in the rock apart. For logging they are different “waters”.

Free formation water
It fills the pores, can move and conducts current. Its resistivity at formation temperature is RwR_w.
Capillary-bound water
The same formation water, but held in small pores and in films on the grains. It is immobile, yet it conducts current in the same way and counts towards water saturation (Capillary pressure and the transition zone).
Clay-bound water
The surface of clay particles holds it, together with the exchangeable cations (positive ions that can be swapped). It adds a conductivity that Archie's equation for clean rocks does not include (Water saturation in shaly sands).
Water of crystallisation
It is part of the crystal lattice of minerals, such as gypsum. It does not conduct current, but it contains hydrogen, so the neutron log sees it.

Salinity of formation waters

Formation waters are solutions of salts. Most of the ions in them are usually sodium Na⁺ and chloride Cl⁻. There are also noticeable amounts of calcium Ca²⁺, magnesium Mg²⁺, potassium K⁺, sulfate SO₄²⁻ and bicarbonate HCO₃⁻. The total content of dissolved salts is called salinity. In Russian-language practice we express it in grams per litre of solution (g/L). In international practice it is often given in ppm (parts per million): milligrams of salt per kilogram of solution. A litre of brine weighs more than a kilogram, so the number in g/L is larger than the number in g/kg.

Converting salinity from g/L to ppm
Cppm=1000 Cg/LρC_\text{ppm} = \frac{1000\,C_{\text{g/L}}}{\rho}
where:
  • CppmC_\text{ppm}salinity in milligrams of salt per kilogram of solution, ppm = mg/kg
  • Cg/LC_{\text{g/L}}salinity in grams of salt per litre of solution, g/L
  • ρ\rhodensity of the solution; for NaCl solutions near 20 °C, approximately ρ≈1+0.73 w\rho \approx 1 + 0.73\,w, where ww is the mass fraction of salt, g/cm³ (= kg/L)

Units: as indicated; Cg/L/ρC_{\text{g/L}}/\rho is grams of salt per kilogram of solution

Holds when
  • The density and the salinity refer to the same temperature.
  • The density formula is an approximation for NaCl solutions at room temperature. For waters of complex composition we measure the density.

For fresh waters the two numbers almost coincide. For brines they differ: 150 g/L at a density of 1.10 g/cm³ is about 136,000 ppm, which is 9% less. Relationships fitted to measurements, and charts, for NaCl solutions are usually built in ppm.

Waters by salinity
Water
Fresh
Salinity
up to 1 g/L
Example
surface waters and shallow groundwater
Water
Brackish
Salinity
1–10 g/L
Example
near the recharge areas of the formations
Water
Saline
Salinity
10–50 g/L
Example
seawater — about 35 g/L
Water
Brine
Salinity
more than 50 g/L
Example
deep horizons, sections with salt-bearing sequences

This is one of the common classifications. A saturated NaCl solution (one that cannot dissolve any more salt) at room temperature contains about 26% salt by mass (about 264,000 ppm, or 316 g/L). Solubility increases only slightly with heating, up to 28% at 100 °C.

Salinity usually increases with depth. Near the surface, rainwater (meteoric water) flushes the formations. In deep, stagnant horizons the water stays in contact with the rocks for a long time. The rule is not absolute. Near the outcrops of formations (where they reach the surface) and in recharge zones (where surface water enters the formation), the water is freshened to a great depth. Near salt-bearing sequences there are brines close to saturation. In some deep horizons salinity decreases again, for example because compacting shales release relatively fresh water. By V. A. Sulin's classification, the waters of oil and gas fields most often belong to the calcium chloride and sodium bicarbonate types.

Log charts and formulas are built for NaCl solutions. For the same mass, other ions conduct current differently: bicarbonate and sulfate are noticeably worse than chloride, and magnesium is better than sodium. So for a water of complex composition we convert the salinity into an equivalent NaCl concentration. This is the sum of the ion concentrations, each multiplied by a weighting coefficient that depends on the total salinity. A more reliable way is to measure the resistivity of the sample directly.

We get the resistivity of the formation water from analyses of samples (formation tests, production), from catalogues of the waters of the area, and from logs: from the SP (Spontaneous potential (SP) log) and from water-bearing zones. We compare the methods with one another (Determining formation water resistivity).

Formation temperature and the geothermal gradient

Heat from the Earth's interior constantly flows towards the surface, so temperature increases with depth. Daily and seasonal changes of air temperature die out within the first few metres. At a depth of 15–40 m there lies a neutral layer with a constant temperature, close to the mean annual air temperature. We take this temperature as the “surface” temperature T0T_0 in calculations. Offshore, we take T0T_0 as the temperature at the seabed. In permafrost regions (ground that stays frozen all year) the upper tens or hundreds of metres of the section have a negative temperature, so linear interpolation from the surface does not work there.

Temperature at depth for a constant gradient
T(z)=T0+GT z,GT=TTD−T0zTDT(z) = T_0 + G_T\,z,\qquad G_T = \frac{T_{TD} - T_0}{z_{TD}}
where:
  • T(z)T(z)temperature of the rocks at depth zz, °C
  • T0T_0mean annual temperature of the surface (neutral layer) or of the seabed, °C
  • GTG_Tgeothermal gradient, °C/m (in practice °C/100 m)
  • zzvertical depth from the surface (for deviated wells, measured vertically, not along the hole), m
  • TTD, zTDT_{TD},\ z_{TD}formation temperature at total depth, and the total depth, °C, m

Units: °C and metres; 1 ∘C/100 m=0.549 ∘F/100 ft1\ ^\circ\text{C}/100\ \text{m} = 0.549\ ^\circ\text{F}/100\ \text{ft}

Holds when
  • The gradient is constant over the section. This is a good approximation for a uniform sedimentary sequence without thick salt layers and without active groundwater movement.
  • TTDT_{TD} is the stabilised formation temperature, not the temperature measured immediately after circulation.

In Russian-language literature, the reciprocal 1/GT1/G_T is called the geothermal step. It is the number of metres we have to go down for the temperature to rise by 1 °C. At GT=3 ∘C/100 mG_T = 3\ ^\circ\text{C}/100\ \text{m} the step is about 33 m.

In sedimentary basins the gradient is usually 2–4 °C per 100 m. In ancient, “cold” platforms it is at the lower end of this range or below. In rifts (zones where the crust is stretching) and in young basins with a high heat flow it is 4–6 °C per 100 m or more. Two quantities determine it: the heat flow qq from the Earth's interior, and the thermal conductivity of the rocks, λ\lambda (how well they conduct heat). By Fourier's law, GT=q/λG_T = q/\lambda. With a typical heat flow of about 60 mW/m² and a thermal conductivity of shales of about 1.5–2 W/(m·K), the gradient comes out at 3–4 °C per 100 m.

  • Salt conducts heat 2–4 times better than shales. So in a thick salt sequence the gradient is small, and below it the rocks are colder than the average gradient would give. Above salt domes, on the contrary, it is warmer.
  • Groundwater movement evens out the temperature: descending flows cool the section, and flows rising along faults warm it.
  • Rapid sedimentation does not give recently buried sequences time to warm up, so the gradient in them is temporarily lower.

We need temperature for more than resistivities. The SP coefficient, the properties of oil, gas and water, the maturation of source rocks (Source rocks, maturation and migration), and the choice of mud, cement and equipment all depend on it. For more on reservoir conditions, see the topic Reservoir pressure and temperature.

Bottom-hole temperature and the correction for circulation

On every run of logging tools we record the bottom-hole temperature (BHT). In the past a maximum-reading thermometer attached to the tool did this; now the tool's own sensors do it. We write the BHT in the log heading together with the depth, the time circulation ended, and the time of the measurement.

But by the time of logging, the well has not yet come into thermal equilibrium with the rocks. While the hole is circulated, the mud brings the cold of the upper intervals down to the bottom and carries heat upwards. Near the bottom the rocks cool down, and higher up the hole they warm up. After circulation stops, the temperature near the bottom recovers slowly, over hours and days. For this reason the temperature measured on the first run is usually below the formation temperature, often by 10 °C or more. The shorter the time since circulation stopped, the larger the shortfall. If we build a gradient from this temperature, all the temperatures over the section come out too low.

If there have been several runs to the same depth, we can extrapolate the temperature from them to infinite time after circulation stops. Temperature recovery follows the same law as pressure recovery after a well is shut in. This is the Horner method (Pressure build-up analysis):

Recovery of the bottom-hole temperature after circulation stops
Tbh(Δt)=Tres−mlg⁡tc+ΔtΔtT_{\text{bh}}(\Delta t) = T_{\text{res}} - m\lg\frac{t_c + \Delta t}{\Delta t}
where:
  • Tbh(Δt)T_{\text{bh}}(\Delta t)temperature at the bottom of the hole a time Δt\Delta t after circulation stops, °C
  • TresT_{\text{res}}formation (stabilised) temperature at this depth, °C
  • mmslope of the line: the drop in temperature per logarithmic cycle (one tenfold change of the ratio). It depends on the cooling power and on the thermal conductivity of the rocks, °C
  • tct_cduration of circulation at this depth before it stopped, h
  • Δt\Delta ttime from the end of circulation to the measurement, h

Units: °C; tct_c and Δt\Delta t in the same units; lg⁡\lg is the decimal logarithm

Holds when
  • The cooling of the bottom of the hole is like the removal of heat by a line source of constant power (a thin line that takes away heat) during tct_c.
  • The readings are taken at one depth, and the time Δt\Delta t is not too short (usually more than a few hours).
  • We need at least three readings (two points cannot show whether the data lie on a line), recorded together with the time circulation stopped.

On a plot of “temperature against lg⁡ [(tc+Δt)/Δt]\lg\,[(t_c + \Delta t)/\Delta t]”, the points lie on a straight line. The value of the line at a ratio equal to one (Δt→∞\Delta t \to \infty) is an estimate of the formation temperature. This is an approximation. When tct_c is not known accurately and the waiting times are short, the error can be several degrees. The most reliable temperature is one measured in a well that has stood for weeks without circulation, or during tests and in production.

Worked exampleFormation temperature from three bottom-hole readings, and the gradient
Given (assumed data)
Total depth (vertical)
3500 m
Duration of circulation before pulling out tct_c
4 h
Bottom-hole readings 6, 12 and 20 h after circulation stopped
109.5, 113.5 and 115.0 °C
Mean annual surface temperature T0T_0
10 °C
Depth of the formation of interest
3080 m
Solution
  1. Abscissae (the horizontal values of the plot): lg⁡(10/6)=0.2218\lg(10/6) = 0.2218, lg⁡(16/12)=0.1249\lg(16/12) = 0.1249, lg⁡(24/20)=0.0792\lg(24/20) = 0.0792.
  2. Slope from the outer points: m=115.0−109.50.2218−0.0792=38.6m = \dfrac{115.0 - 109.5}{0.2218 - 0.0792} = 38.6 °C per cycle. The middle reading deviates from this line by only 0.3 °C, so the points do lie on a straight line.
  3. Extrapolation to Δt→∞\Delta t \to \infty: Tres=115.0+38.6⋅0.0792=118.1T_{\text{res}} = 115.0 + 38.6\cdot 0.0792 = 118.1 °C. A least-squares line through all three points (the line that fits them best) gives 118.2 °C.
  4. Gradient: GT=(118.1−10)/35=3.09G_T = (118.1 - 10)/35 = 3.09 °C per 100 m (a depth of 3500 m is 35 hundreds of metres; 1.69 °F per 100 ft). The geothermal step is 32 m.
  5. Temperature of the formation at 3080 m: T=10+3.09⋅30.8=105T = 10 + 3.09\cdot 30.8 = 105 °C. If we had built the gradient from the first reading of 109.5 °C, we would have got 97.6 °C, which is 7.5 °C lower.
Answer: The formation temperature at total depth (the bottom of the well) is about 118.1 °C, the gradient is 3.09 °C per 100 m, and the temperature of the formation of interest is about 105 °C.

What it means. The first reading put the formation temperature at total depth too low by 8.6 °C. This temperature goes into the conversion of the resistivities of water and filtrate (the example below), into the SP coefficient, and into calculations of fluid properties. The extrapolation is an estimate. If the circulation time is not known accurately, we check the result against measurements made during a formation test. The data in this example are assumed for illustration.

Bottom-hole temperature after circulation stops, in Horner coordinates321.51.21100105110115120Ratio (tc + Δt) / ΔtBottom-hole temperature, °Cformation ≈ 118 °C6 h12 h20 h

Chart: the horizontal axis is the Horner ratio from 3 to 1 on a logarithmic scale, the vertical axis is temperature from 98 to 120 °C. Three points — 109.5 °C at a ratio of 1.67 (after 6 h), 113.5 °C at 1.33 (12 h) and 115 °C at 1.2 (20 h) — lie on an inclined dashed line, which continues to the right to a ratio of 1 and ends at a mark of about 118 °C, the estimate of the formation temperature.

CalculatedThe bottom-hole temperature readings of the example in Horner coordinates. The horizontal axis is the ratio (tc+Δt)/Δt(t_c + \Delta t)/\Delta t on a logarithmic scale (time increases to the right). The line is drawn through the outer points and extended to a ratio equal to one.

Water resistivity: salinity and temperature

Ions create the electrical conductivity of water. The more salt is dissolved, the more charge carriers there are and the lower the resistivity, though not in proportion: in strong solutions the ions get in each other's way. When water is heated, it becomes less viscous, the ions move faster, and near 25 °C the conductivity rises by about 2% per degree. From 20 to 100 °C the resistivity of a solution decreases almost threefold.

Resistivity of an NaCl solution at 24 °C from its concentration
R24≈0.0123+3647.5Cppm 0.955R_{24} \approx 0.0123 + \frac{3647.5}{C_\text{ppm}^{\,0.955}}
where:
  • R24R_{24}resistivity of the solution at 24 °C (75 °F), Ω·m
  • CppmC_\text{ppm}concentration of NaCl (or equivalent NaCl concentration), ppm

Units: empirical: RR in Ω·m, CC in ppm

Holds when
  • An empirical approximation (a formula fitted to tables of measurements) for NaCl solutions, from hundreds of ppm to nearly saturated. The error is usually within a few per cent, and larger for nearly saturated brines.
  • For a water of another composition, CC is the equivalent NaCl concentration.

Seawater (about 35,000 ppm) has about 0.18 Ω·m at 24 °C, a 100,000 ppm brine about 0.07 Ω·m, and a saturated solution about 0.04 Ω·m. Resistivity falls more slowly than concentration rises: a tenfold increase in salinity reduces RR by about a factor of eight.

Converting the resistivity of a solution to another temperature (the Arps formula)
R2=R1 T1+21.5T2+21.5R_2 = R_1\,\frac{T_1 + 21.5}{T_2 + 21.5}
where:
  • R1, R2R_1,\ R_2resistivity of the solution at temperatures T1T_1 and T2T_2, Ω·m
  • T1, T2T_1,\ T_2temperatures, °C

Units: °C; the resistivities in any identical units

Holds when
  • An empirical approximation for NaCl solutions in the usual range of formation temperatures.
  • In logging we apply it to all aqueous solutions: formation water, filtrate and drilling mud. For mudcake and for waters of complex composition the accuracy is lower.

Resistivity is inversely proportional to the sum T+21.5T + 21.5: as if conductivity grew linearly with temperature and vanished at −21.5 °C. The formula does not depend on salinity, so the same water, when heated from 20 to 100 °C, becomes 121.5/41.5≈2.9121.5/41.5 \approx 2.9 times more conductive.

In other unit systems (2)
Temperature in °F
R2=R1 T1+6.77T2+6.77R_2 = R_1\,\frac{T_1 + 6.77}{T_2 + 6.77}

T1T_1, T2T_2 in degrees Fahrenheit.

The sum T+6.77T + 6.77 vanishes at −6.77 °F — the same point as −21.5 °C: 1.8⋅(−21.5)+32≈−6.71.8\cdot(-21.5) + 32 \approx -6.7.

Form with a temperature coefficient
ρw(t)=ρw(18)1+α (t−18)\rho_\text{w}(t) = \frac{\rho_\text{w}(18)}{1 + \alpha\,(t - 18)}

tt in °C, ρw(18)\rho_\text{w}(18) is the resistivity of the water at 18 °C; this is how the correction is often written in Russian-language literature.

At α=1/39.5≈0.025 ∘C−1\alpha = 1/39.5 \approx 0.025\ ^\circ\text{C}^{-1} the formula coincides with the Arps formula: 18+21.5=39.518 + 21.5 = 39.5.

Resistivity of NaCl solutions of different concentrations against temperature02550751001251500.010.020.050.10.20.512Temperature, °CSolution resistivity, Ω·m20 °C: 0.123 Ω·m105 °C: 0.040 Ω·m10 g/kg59 g/kg — example water200 g/kg

Chart: the horizontal axis is temperature from 0 to 150 °C, the vertical axis is resistivity on a logarithmic scale from 0.01 to 2 Ω·m. Three smoothly decreasing curves: the upper one is 10 grams of salt per kilogram of solution, from 0.82 at 10 °C to 0.15 Ω·m at 150 °C; the middle one is 59 g/kg, the water of the example; the lower one is 200 g/kg. Two points are marked on the middle curve: 0.123 Ω·m at 20 °C and 0.040 Ω·m at 105 °C.

CalculatedResistivity of NaCl solutions of three concentrations against temperature, calculated with the two formulas above. The middle curve is the water of the example below; the points are its resistivity at 20 °C in the laboratory and at the formation temperature of 105 °C.
Worked exampleFormation water resistivity from an analysis of a sample
Given (assumed data)
Salinity of the sample (almost entirely NaCl)
62 g/L
Density of the sample at 20 °C
1.043 g/cm³
Resistivity of the sample measured in the laboratory
0.123 Ω·m at 20 °C
Formation temperature
105 °C (from the previous example)
Solution
  1. Concentration in ppm: C=1000⋅62/1.043=59,444C = 1000\cdot 62/1.043 = 59{,}444 ppm (59.4 g/kg). Density check: 1+0.73⋅0.0594=1.0431 + 0.73\cdot 0.0594 = 1.043 g/cm³ — consistent with the measurement.
  2. Resistivity at 24 °C from the concentration: R24=0.0123+3647.5/59,4440.955=0.113R_{24} = 0.0123 + 3647.5/{59{,}444}^{0.955} = 0.113 Ω·m.
  3. The laboratory measurement converted to 24 °C: 0.123⋅41.5/45.5=0.1120.123\cdot 41.5/45.5 = 0.112 Ω·m — a discrepancy of 0.7%: the sample really is close to an NaCl solution.
  4. At formation temperature: Rw=0.123⋅20+21.5105+21.5=0.040R_w = 0.123\cdot\dfrac{20 + 21.5}{105 + 21.5} = 0.040 Ω·m; from the concentration it comes out as 0.041 Ω·m.
  5. If we take the uncorrected temperature of 97.6 °C from the previous example, Rw=0.043R_w = 0.043 Ω·m — 6% more.
Answer: The resistivity of the formation water at formation temperature is about 0.040 Ω·m, three times lower than the laboratory value.

What it means. By Archie's equation, for n=2n = 2, the water saturation is proportional to Rw\sqrt{R_w} (Archie's equation and saturation of clean reservoirs). If we put in the laboratory value of 0.123 Ω·m, SwS_w comes out too high by a factor of 1.75. A formation with a true water saturation of 30% would then appear to be 52% water-saturated. If the temperature is too low by 7.5 °C and nobody notices, the cost is smaller: about 3% in SwS_w. Even that should not be neglected. The data in this example are assumed for illustration.

Terms and symbols

Salinity
The total content of dissolved salts in water, in g/L or ppm.
ppm
Milligrams of salt per kilogram of solution. It equals 1000 Cg/L/ρ1000\,C_{\text{g/L}}/\rho.
Equivalent NaCl concentration
The concentration of an NaCl solution with the same electrical conductivity as a water of complex composition.
Formation water resistivity RwR_w
The resistivity of the water in the pores at formation temperature.
Geothermal gradient GTG_T
The increase of temperature per unit of depth, in °C/100 m. Its reciprocal is the geothermal step, in m/°C.
Neutral layer
A layer at a depth of 15–40 m with a constant temperature, close to the mean annual one. It gives the datum for the “surface” temperature.
Bottom-hole temperature (BHT)
The temperature measured by a tool at the bottom of the hole. Because circulation cools the bottom, it is usually below the formation temperature.
Circulation time tct_c and time since it stopped Δt\Delta t
The input data for correcting the bottom-hole temperature by the Horner method.

Common mistakes and misconceptions

Wrong

“The bottom-hole temperature from the first tool run is the formation temperature.”

In fact

Circulation cools the bottom of the hole, and the first readings are below the formation temperature, often by 10 °C or more. We get the formation temperature by extrapolating several readings, by regional corrections, or from measurements in wells that have stood idle.

Wrong

“The resistivity of a sample measured in the laboratory is RwR_w.”

In fact

That is the resistivity at laboratory temperature. At a formation temperature of 100 °C it is almost three times lower. Without conversion, the water saturation is overestimated by a factor of about 1.7.

Wrong

“A gram per litre and ppm are practically the same thing.”

In fact

For fresh waters they are; for brines they are not. The number in ppm is smaller than the number in mg/L by the factor by which the density of the solution exceeds 1 g/cm³: for brines, by 3–17%.

Wrong

“The temperature gradient is the same throughout the section.”

In fact

It is inversely proportional to the thermal conductivity of the rocks: smaller in salt, larger in shales. Water movement and rapid sedimentation change it too. Linear interpolation is an approximation for uniform sequences.

Wrong

“The RwR_w of any water can be found from its total salinity with the NaCl formulas.”

In fact

Only for waters close to an NaCl solution. For waters with a large share of calcium, magnesium, sulfates and bicarbonates, we need the equivalent NaCl concentration or a direct measurement of the resistivity of the sample.

In depth: advanced detail

Where the logarithm in the circulation correction comes from

Imagine that circulation removes heat from the rocks at a constant power QQ per metre of borehole for a time tct_c, and then stops. The conduction of heat towards the borehole follows the same diffusion equation as fluid flow towards a well. So the solution repeats the line-source solution (Line-source solution and the pressure function). After the stop, the temperature equals the formation temperature, minus the cooling from a “sink” that has worked since time 0, plus the heating from an equal “source” switched on at the moment of the stop. This is the principle of superposition (adding the effects of separate causes) (Superposition principle).

At long times the exponential integrals are replaced by logarithms, and the difference of the two solutions gives Tres−Tbh=Q4πλln⁡tc+ΔtΔtT_{\text{res}} - T_{\text{bh}} = \dfrac{Q}{4\pi\lambda}\ln\dfrac{t_c + \Delta t}{\Delta t}, where λ\lambda is the thermal conductivity of the rocks. If we change to the decimal logarithm, we get the slope m=2.303 Q/(4πλ)m = 2.303\,Q/(4\pi\lambda). This is exactly the slope used in the example of the lesson. The approximation works when Δt\Delta t is much longer than the time rw2/(4a)r_w^2/(4a), where a≈10−6a \approx 10^{-6} m²/s is the thermal diffusivity of the rocks (how fast a temperature change spreads through them). For a hole of radius 0.11 m this time is less than an hour.

Connections to other topics

Check yourself

  1. 1

    The mean annual surface temperature is 12 °C, and the stabilised temperature at a depth of 2500 m is 87 °C. What is the geothermal gradient?

    1. A.2.5 °C/100 m
    2. B.3.0 °C/100 m
    3. C.3.5 °C/100 m
    4. D.4.0 °C/100 m
    Show the answer

    Correct answer: B. 3.0 °C/100 m

    GT=(87−12)/2500=0.030G_T = (87 - 12)/2500 = 0.030 °C/m, that is 3.0 °C per 100 m; the geothermal step is about 33 m per degree.

  2. 2

    The resistivity of a formation water sample is 0.20 Ω·m at 25 °C. What will it be at a formation temperature of 90 °C?

    Show the answer

    By the Arps formula: R=0.20⋅(25+21.5)/(90+21.5)=0.20⋅46.5/111.5≈0.083R = 0.20\cdot(25 + 21.5)/(90 + 21.5) = 0.20\cdot 46.5/111.5 \approx 0.083 Ω·m — 2.4 times lower.

  3. 3

    On three successive tool runs the bottom-hole temperature rose: 96, 101 and 103 °C. What does this mean?

    1. A.The tools are faulty
    2. B.The bottom of the hole is warming up after circulation stopped, and the formation temperature is above 103 °C
    3. C.The formation is cooling over time
    4. D.The formation temperature is the average of the three readings, 100 °C
    Show the answer

    Correct answer: B. The bottom of the hole is warming up after circulation stopped, and the formation temperature is above 103 °C

    Circulation cooled the rocks near the bottom. After it stopped, the temperature has been recovering towards the formation temperature. The last reading has not yet reached equilibrium. We find the formation temperature by extrapolation in Horner coordinates.

  4. 4

    Brine analysis: 150 g/L, density 1.10 g/cm³. How much is that in ppm, and why does the difference matter for charts?

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    C=1000⋅150/1.10≈136,000C = 1000\cdot 150/1.10 \approx 136{,}000 ppm. Charts and empirical formulas for NaCl are built in ppm (mass fractions). If we put in 150,000, RwR_w comes out too low, and for a brine an error of 10% in concentration is noticeable.

  5. 5

    In which section, for the same heat flow, will the geothermal gradient be smallest?

    1. A.In a thick shale sequence
    2. B.In a thick sequence of rock salt
    3. C.In water-bearing sandstones
    4. D.The gradient does not depend on the rocks
    Show the answer

    Correct answer: B. In a thick sequence of rock salt

    By Fourier's law GT=q/λG_T = q/\lambda. The thermal conductivity of salt is 2–4 times higher than that of shales, so in a salt-bearing sequence temperature increases with depth more slowly.

  6. 6

    Water saturation was calculated by Archie's equation with an RwR_w measured at 20 °C, although the formation is at 110 °C. What are the sign and the approximate scale of the error?

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    The true RwR_w is lower than the laboratory value by a factor of (110+21.5)/(20+21.5)≈3.2(110 + 21.5)/(20 + 21.5) \approx 3.2. At n=2n = 2 water saturation is proportional to Rw\sqrt{R_w}, so it is overestimated by a factor of about 3.2≈1.8\sqrt{3.2} \approx 1.8 — a productive bed may appear to be water-bearing.

Updated: 26 October 2026